Dipyrrin based luminescent cyclometallated palladium and platinum complexes.

نویسندگان

  • Catherine Bronner
  • Stéphane A Baudron
  • Mir Wais Hosseini
  • Cristian A Strassert
  • Aurélie Guenet
  • Luisa De Cola
چکیده

A series of complexes based on the combination of cyclometallated palladium or platinum moieties with functionalized dipyrrin ligands bearing mesityl- or benzonitrile groups have been prepared and characterized both in the solid state and in solution; these compounds exhibit a characteristic dipyrrin-centered luminescence with an emission intensity modulated by the degree of rotational freedom of the aromatic group attached to the dipyrrin chelate.

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عنوان ژورنال:
  • Dalton transactions

دوره 1  شماره 

صفحات  -

تاریخ انتشار 2010